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Limestone iron coating and its phosphorus removal improvement
Received:March 15, 2020  
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KeyWord:constructed wetland;total P;limestone;iron coating
Author NameAffiliationE-mail
SHI Jia-cheng College of Natural Resources and Environment, South China Agricultural University, Guangzhou 510642, China  
CHEN Can-ming College of Natural Resources and Environment, South China Agricultural University, Guangzhou 510642, China  
GAO Ting College of Natural Resources and Environment, South China Agricultural University, Guangzhou 510642, China  
WEI Ze-bin College of Natural Resources and Environment, South China Agricultural University, Guangzhou 510642, China  
WU Qi-tang College of Natural Resources and Environment, South China Agricultural University, Guangzhou 510642, China wuqitang@scau.edu.cn 
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Abstract:
      In order to obtain a low-cost iron coating method suitable to constructed wetland substrate for rural domestic sewage treatment, this study compared limestone and river sand as substrates for Fe-coating in laboratory experiments, using three types of Fe-containing solutions:FeCl3, FeSO4 and Fe(OH)3 colloids. Four methods were employed for the addition of these Fe solutions:soaking the substrate in the solution without re-collecting, re-collecting after soaking for 2 h, re-collecting immediately after soaking for 1 min, and spraying Fe solutions onto the substrate. Three drying methods, drying at 105℃, drying under sun-right, and natural drying under roof, were compared. A small constructed wetland filled with Fe-coated limestone was set-up and operated to verify its effectiveness. The method of Fe coating as per the laboratory experiments is as follows:The limestone is immersed in a 1.5 mol·L-1 FeSO4 solution, re-collect the limestone after the full contact with the FeSO4 solution for 1 min, and the Fe-containing liquid film on the limestone dried naturally under roof. The batch adsorption test showed that the removal rate of total P from domestic sewage by limestones was improved from 22.7% to 80.6% for the Feloaded limestone. The removal rate of total P by constructed wetland with Fe-coated limestone was increased by 10% to 15% compared with the ordinary limestone wetland.