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Adsorption of Pb by biochars derived from two types of biomass
Received:March 04, 2017  
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KeyWord:camellia shell;biochar;adsorption;Pb2+
Author NameAffiliationE-mail
YANG Ting-ting College of Environmental Science and Engineering, Yangzhou University, Jiangsu 225127, China  
MENG Li-rong College of Environmental Science and Engineering, Yangzhou University, Jiangsu 225127, China  
LI Hui Yangzhou Environmental Protection Bureau, Yangzhou, 225002  
WU Ji-yang College of Environmental Science and Engineering, Yangzhou University, Jiangsu 225127, China  
YIN Wei-qin College of Environmental Science and Engineering, Yangzhou University, Jiangsu 225127, China  
WANG Sheng-sen College of Environmental Science and Engineering, Yangzhou University, Jiangsu 225127, China  
HOU Jian-hua College of Environmental Science and Engineering, Yangzhou University, Jiangsu 225127, China  
WANG Xiao-zhi College of Environmental Science and Engineering, Yangzhou University, Jiangsu 225127, China
Jiangsu Collaborative Innovation Center for Solid Organic Waste Resource Utilization, Nanjing 210095, China 
xzwang@yzu.edu.cn 
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Abstract:
      Two raw materials, i.e., rice bran and camellia shell, were used to produce biochars via pyrolysis at 650℃. The physical and chemical properties of biochars were characterized by scanning electron microscopy(SEM), X-ray diffraction(XRD), and Brunauer-Emmett-Teller(BET) surface area analyses. The effects of particle size, mineral composition, contact time, and initial Pb2+ concentration on Pb2+ adsorption by biochars were examined. The results showed that compared to rice bran-derived biochar, camellia shell-derived biochar had smaller specific surface area, but was more effective in removing heavy metals from aqueous solutions. The adsorption isotherm of Pb2+ by camellia shell-derived biochar fit the Langmuir model well, and the adsorption capacity was 165.62 mg·g-1, which was higher than that of rice bran-derived biochar(58.92 mg·g-1). The results of XRD analysis showed that camellia shell-derived biochar contained a large amount of mineral components and appeared as a precipitate after adsorption.